Total alkalinity is a fundamental chemical parameter in drinking water, defined as the capacity of water to neutralise strong acids. It primarily reflects the presence of bicarbonate, carbonate, and hydroxide ions. Alkalinity influences buffering capacity, corrosivity, taste, and the stability of distribution systems. Yet, despite its importance, there is no single globally accepted standard value for normal drinking water alkalinity. Requirements vary significantly across countries and regulatory frameworks.
China’s National Standard
Under the current Standards for Drinking Water Quality (GB 5749-2022), total alkalinity is not listed as a mandatory routine or expanded indicator. The standard does not prescribe a specific limit for alkalinity. By contrast, total hardness (as CaCO₃) is regulated with a maximum limit of 450 mg/L.
Some references indicate that the previous version, GB 5749-2006, included a reference value of 450 mg/L (as CaCO₃) for total alkalinity, but this value no longer appears as a mandatory requirement in the 2022 edition. In practical water treatment, some industry guidelines recommend that reverse osmosis permeate maintain alkalinity above 50 mg/L (as CaCO₃) primarily to control pipe corrosion.
World Health Organization Guidelines
The WHO Guidelines for Drinking-water Quality does not classify alkalinity as a health‑based parameter and therefore does not set a health guideline value. However, in WHO water quality reference tables, total alkalinity is often cited around 200 mg/L (as CaCO₃), with some documents indicating a reference range of 200–600 mg/L. These figures serve as technical guidance for national standard‑setting rather than enforceable limits.
Indian Standards (BIS)
The Bureau of Indian Standards (BIS) provides one of the clearest regulatory frameworks for alkalinity in drinking water. Under IS 10500, the acceptable limit for total alkalinity (as CaCO₃) is 200 mg/L, with a permissible upper limit of 600 mg/L in the absence of an alternative source. This dual‑tier approach reflects both desirable quality goals and practical relaxation for unavoidable circumstances.
United States EPA Practice
The USEPA does not classify alkalinity as a primary enforceable contaminant. Instead, alkalinity is treated as an operational parameter, used to assess buffering capacity and corrosion potential in distribution systems. pH, which is closely related to alkalinity, is regulated as a secondary (aesthetic) contaminant with a recommended range of 6.5–8.5.

